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Determining the Pollutant Emission Rate from a Source
Meeting the Needs of Industry
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The emission rate of a pollutant is the product of the measured pollutant concentration and the measured effluent flow rate. In order to make this work, the volume must be expressed in the same terms i.e. standard or  
  reference conditions. In Canada, reference conditions (R) are 25°C and 101.3 kPa. In the United States, standard conditions (S) are 68°F and 29.92 in Hg.

Pollutant Concentration (mg/R.m³) x Effluent Flow Rate (R.m³/s) = Pollutant Mass Rate mg/s

Volumes and volumetric rates measured at Actual Conditions (A) can be converted to Reference or Standard Conditions using the universal gas laws.

Instrumental analyzers typically report pollutant concentrations on a part per million volume basis (ppmv). This unit needs to be converted to a mass per unit volume basis (mg/m³) in order to determine the mass rate of the pollutant.

This is accomplished using the formula below:

Where:
MW is the molecular weight of the pollutant gas i.e. 64 g/gmole for SO2
MV is the molar volume at reference or standard conditions i.e. 24.45 L/mole at 25°C and 1 atm